dsc graph interpretation pdf

DSC-TGA (SDT): The Technique Q600 SDT Simultaneous DSC-TGA: Measures heat flow and weight changes simultaneously Simultaneous DSC-TGA measures both heat flow and weight changes in a material as a function of temperature or time in a controlled atmosphere. G�YecJ0�[:&ႉ�zq6s>Xl��%J�_S��F��,R�"��? 8. The peak temperature is an important experimental value in DSC measurements. endobj Data Interpretation: The output of a DSC is a plot of heat flux (rate) versus temperature at a specified temperature ramp rate. For example, tables do not need to be boxed in with lines surrounding each value. <>/Metadata 650 0 R/ViewerPreferences 651 0 R>> DSC Measurements of Epoxy Adhesives 1. 1202 0 obj <>/Filter/FlateDecode/ID[<8396A40228C5ED45AC5751051A60CB23>]/Index[1165 51]/Info 1164 0 R/Length 156/Prev 1324854/Root 1166 0 R/Size 1216/Type/XRef/W[1 3 1]>>stream One general limitation depicted is the possibility of multiple interpretations of a single measurement signal which sometimes makes definite identification difficult. The heat flux can be converted to CP by dividing by the constant rate of temperature change. The higher the thermal transition midpoint (Tm), the more stable the molecule. Systematic differences in this quantity can occur depending on the measurement conditions and the origin of the peak. DSC Although DSC is a simple, convenient and fast technique to measure lipid oxidation, some recommended guidelines should be considered to obtain reliable and reproducible results. The current field of thermal analysis is both diverse and dynamic. 5 Q What can we learn from this TGA Thermal Curve? <> 3 DSC Training Course Second Generation Q-Series™ DSCs Q2000 Q200 AutoQ20 It is also used to determine the change in heat capacity (ΔCp) of denaturation. Conveying information efficiently goes along with frugal use of "non-data ink". 3.1 Heat Flux DSC In a heat ux DSC system the sample and reference are heated at the same rate from a single heating source as shown in Figure 6. Generally, the non-isothermal DSC is used for the identification of neat basic polymers as well as the determination of their purity and stability. The curve should now be cut into DSC can elucidate the factors that contribute to the folding and stability o… h�b```b``�g`c`�� ̀ ��@Q��ln|:5qe��F�m^00�)2h>x��TH��^��K�b�U�.+ͪJ�-X2��H�c�U�:/�)'�^�X��6o�OP}WӤ̗&'w5)O��д�� -l�B�;:��+@��b� �Ł��B|n@Z ��~ad�˨�`��郜�{�6�ë= [�i�u�n��0m�k��4NKG�p��8�V�C_v73��s&��dU�r�?��o�9�J��د��8�q�r�h��_O�k�r첊E��V�. The DSC graph showing "ACV-1" is for a pure drug while "PM-1" is the graph of a physical mixture of that drug along with two other polymers. The measurement signal is the energy absorbed by or released by the sample in milliwatts. During curing, the epoxy group starts a polymerization reaction, cross-links and Although not a new field, more advanced instrumentation, techniques and applications are constantly appearing on the market and in the literature. In this case of calcium carbonate we know: • CaCO 3 is an irritant! A We must first list all pertinent information we know about the sample before we can analyze the data. After molding, the plastic has crystalline and amorphous regions. DSC analysis is used to measure melting temperature, heat of fusion, latent heat of melting, reaction energy and temperature, glass transition temperature, crystalline phase transition temperature and energy, precipitation energy and temperature, denaturization temperatures, oxidation induction times, and specific heat or heat capacity. h�bbd```b``�".�HF��"Y��L�`v3X�$�T �� L6�E��Un�D�Șb��lr*��Q�ˀ$��R{H��T[q-��9g�b+��؊ ��#��D*�I5��~�1012�Ȃ}��H��ߚ� �� Thus, DSC curve could be used to infer about the presence of a particular compounds and its thermal behaviour. In DSC, the heat flow to and from a sam-ple and a reference material is measured as a function of temperature as the sam-ple is heated, cooled or held at constant temperature. A biomolecule in solution is in equilibrium between its native (folded) and denatured (unfolded) conformations. Both the sample and reference are maintained at nearly the same temperature throughout the experiment. ; so be careful handling the sample, wear eye protection • It is hygroscopic (it absorbs or attracts moisture from the air). 0 %PDF-1.6 %�� The interpretation of a DSC measurement curve is therefore still some-thing you have to do yourself. Interpretation of DSC Curve: DSC curve of a pure compound is a fingerprint of in which compound in the context of transition temperature as well as heat needed for that transition. Differential scanning calorimetry (DSC) is a thermoanalytical technique in which the difference in the amount of heat required to increase the temperature of a sample and reference is measured as a function of temperature. 4 0 obj Common materials include foods, pharmaceuticals, electronic materials, polymers, ceramics, organic and inorganic compounds, even biological organisms… Besides providing a wealth of information, Differential Scanning Calorimetry (DSC) is user-friendly in terms of sample preparation, experimental configuration, and interpretation of the results. Polyethylene terephthalate or PETE, is a commonly used plastic in food packaging, including beverage bottles: PETE is a semi-crystalline polymer. 1215 0 obj <>stream Differential Scanning Calorimetry (DSC) – provides information about thermal changes that do not involve a change in sample mass11 – more commonly used technique than TGA – Two basic types of DSC instruments: heat-flux and power compensation 1Haines, P. J. hެVmo�H�++ݗT�t��k�T!M��B��C|p`�Ʀ�I��,��&��xǳ3��>;FH�gBr��H �)�i�2m��)�L@��z �A`I�LD�0�b(�4ͤ�!��8q� fL�1c��É�l�O�l�j��i��D�^��䒸tRG��nq��t��ˋ�p�R�mw��]��뿈��C��e-�g�!�\��/�$� A sample of known mass is heated or cooled and the changes in its heat capacity are tracked as changes in the heat flow. Interpreting DSC Data 3 Splitting a Curve into Segments To cut a measurement curve into segments users will need to left-click on their curve of interest, causing it to turn white. From this menu select the “Split Into Segments” option. Determination of the melting temperature, heat of fusion, and purity analysis of different samples of zidovudine (AZT) using DSC 39 F- fraction of sample melted at T m, R- gas constant, 8.314 J mol-1 deg. To obtain the graph of T m x 1/F from the DSC curve, some points, normally within the region between 10 and 50% of the peak, are evaluated. DSC measures the enthalpy (H) of unfolding that results from heat-induced denaturation. Introduction Epoxy adhesives are often used as adhesives and fillers for materials such as metal, glass, ceramic, and plastic. 89 Use of heat flows from DSC curve for calculation of specific heat of the solid materials E. Morîntale1, A. Harabor1, C. Constantinescu2, P. Rotaru1 1University of Craiova, Faculty of Physics, 13 A.I. endobj Differential scanning calorimetry (DSC) measures the energy absorbed (endotherm) or produced ... curing peak on the DSC curve. %%EOF stream DSC Interpretation Notes 1 of 4 Cooper/Glasgow 25/04/01 DSC Interpretation Notes-- Alan Cooper (Glasgow) These notes are intended to help in the interpretation, avoiding over-interpretation, of biomolecular DSC data (mainly for proteins). 2 DSC Training Course 2900 Series DSC’s DSC 2010 DSC 2910 DSC 2920 DSC Training Course Q1000 Q100 Q10 First Generation Q Series™ DSCs. This work is about the identification of polymers by means of differential scanning calorimetry (DSC), thermogravimetry (TG) and simultaneous thermal analysis (STA) involving computer-assisted database search. 3 DSC Instructions Two types of DSC instruments are widely used: the heat ux DSC (eg. It requires a considerable amount of experience in thermal H33�m�� d�0��(g�0 �}� The DSC Analysis Technique. Differential Scanning Calorimetry (DSC) Differential Scanning Calorimetry (DSC) is an analytical technique which measures the heat flow into or out of a sample as a function of time and/or temperature. <> The output from a DTA is temperature … Theoretically, almost any substance whether solid, semi-solid or liquid can be analyzed and characterized with thermal analytical techniques. A Differential Scanning Calorimetry, or DSC, is a thermal analysis technique that looks at how a material’s heat capacity (Cp) is changed by temperature. This tool features many powerful techniques for studying polymer thermal properties and provides essential information to the polymer industry and end users of polymer-based products. They should be read in conjunction with more comprehensive treatments, some of which are listed at the end. DSC allows you to detect endothermic endobj 9. Then, users will right click on the same curve to display a menu. Interpreting DSC curves Part 1: Dynamic measurements The art of interpreting curves has yet to be integrated into commercially available com-puter programs. Differential scanning calorimetry is a specific type of calorimetry including both a sample substance and a reference substance, residing in separate chambers. This paper will provide an overview of DSC. These thermosetting adhesives are mainly created from epoxy resins and curing agents. Plots showing differences in heat flow between a sample and reference, as a function of time Interpretation of Undesirable Events in DSC Data Applications. because DSC is easy-to-use, DSC has become the most commonly used thermal analysis technique. obscure the main message of the table or graph. The article explains the reasons for these differences and discusses the possibilities for … One of the tools proven to address these needs is differential scanning calorimetry (DSC). x��UQo�0~��G�Vc�A�*am�DMS5E}�)��:�1WS��lHP��F��qw>�w��ֲ|�WNO�P�|��x��m�wv��-�E�.�\��N��6]�CQ��A4�ᗁ&� (\�ԅ�n?Ae�(3��s! Glass Transition Temperature by DMA 150.49°C 156.10°C 151.64°C Polycarbonate 1Hz, 15µm amplitude 3°C/min 0.0 0.5 1.0 1.5 Tan Delta 0.1 1 10 100 1 <>/ExtGState<>/ProcSet[/PDF/Text/ImageB/ImageC/ImageI] >>/MediaBox[ 0 0 612 792] /Contents 4 0 R/Group<>/Tabs/S/StructParents 0>> %PDF-1.7 This allows the detection of transitions such as melts, There are, however, some common DSC events/ transitions that can be the cause of less than optimum results and/or misinterpretation. Differential scanning calorimetry (DSC) is a physical characterization method used to study thermal behavior of neat polymers, copolymers, polymer blends and composites. {4UN(8�X��vn��9�dQ['��YV7��d�JT�k��s�:�&�/��e�Z��$�� 3�8��8﬌`��#�� s]�9�{�d��@��c {��p��V0LT��?HTL�A�Z�Y2_\�,�(3��3̵f�ʹ1͎;��t��,�T�D�|�F��B �B��B��f�b��j��1e��9V ,P tJ�6"��͑��C�o��k{�~ۆh. 1165 0 obj <> endobj Draft View has the fastest screen update of the four view modes. For example, ... • The bottom right frame shows a live graph of your data once the test has started. %�� … Interpretation and analysis of DSC data may be difficult for some samples. Similarly, "perspective" should not be added to two-dimensional charts and graphs, as it impedes quick and correct interpretation. TA DSC and Mettler DSC) and the power compensated DSC (Perkin-Elmer system). In Draft View, the page automatically sizes to fill the graph window. This is a … 1 0 obj Ease-of-use in this case refers to sample preparation and experimental setup, as well as interpretation of the results. Among those guidelines are the pre-treatment and sample preparation, amount of sample used, heating protocol, gas flow rate, and interpretation of DSC thermograms. Differential scanning calorimetry• This technique is used to study what happens to polymers/samples upon heating• It is used to study thermal transitions of a polymer/sample (the changes that take place on heating) – For example: • The melting of a crystalline polymer • The glass transition • The crystallization 3. endstream endobj startxref DSC Data Analysis in Origin ... other objects in a graph window that reside in the gray area of the page are not visible in Window View mode. 3 0 obj I~̝ä$u�a��g��&˃AΙ,�"�lj��3 7�y��!A�@h��m��,`j�{��`��t�?�� p��ҌA�Y?�f�m��9��, �� Simultaneous measurement of … endstream endobj 1166 0 obj <>/Metadata 66 0 R/OpenAction 1167 0 R/PageLayout/SinglePage/Pages 1163 0 R/StructTreeRoot 93 0 R/Type/Catalog/ViewerPreferences<>>> endobj 1167 0 obj <> endobj 1168 0 obj <>/ExtGState<>/Font<>/ProcSet[/PDF/Text/ImageC]/Properties<>>>/XObject<>>>/Rotate 0/StructParents 3/TrimBox[0.0 0.0 594.0 792.0]/Type/Page>> endobj 1169 0 obj <>stream 1.5 DSC Differential Scanning Calorimetry. 2 0 obj DSC of PETE 4 The second direct information obtainable from DSC thermograms is the enthalpy associated with first order processes. The DSC graph showing "ACV-1" is for a pure drug while "PM-1" is the graph of a physical mixture of that drug along with two other polymers. Its thermal behaviour to infer about the sample before we can analyze the data one general limitation depicted the... Current field of thermal analysis is both diverse and dynamic the table or graph as changes in its heat (... Semi-Solid or liquid can be analyzed and characterized with thermal analytical techniques, semi-solid or can... Used as adhesives and fillers for materials such as metal, glass ceramic. That can be converted to CP by dividing by the constant rate of temperature.!, glass, ceramic, and plastic analyzed and characterized with thermal analytical techniques can. Same temperature throughout the experiment frame shows a live graph of your data once the test started... In thermal obscure the main message of the peak temperature is an irritant mainly created from Epoxy and... • CaCO 3 is an important experimental value in DSC measurements at the. Thermal behaviour transitions that can be analyzed and characterized with thermal analytical techniques heat flux can be the cause less... Is therefore still some-thing you have to do yourself, as well as interpretation of a particular compounds its! Δcp ) of denaturation multiple interpretations of a DSC measurement curve is therefore still you!, is a commonly used plastic in food packaging, including beverage bottles: PETE is dsc graph interpretation pdf polymer... To address these needs is differential scanning calorimetry ( DSC ) and denatured ( unfolded ).... Considerable amount of experience in thermal obscure the main message of the results correct.! Experimental value in DSC measurements first list all pertinent information we know: • CaCO 3 is an experimental. And amorphous regions ink '' added to two-dimensional charts and graphs, as well as the determination of purity. And plastic is in equilibrium between its native ( folded ) and the changes in its capacity! Data may be difficult for some samples select the “ Split Into Segments ” option solution is in equilibrium its. As well as the determination of their purity and stability, as it impedes quick correct! Your data once the test has started polymers as well as interpretation of the peak temperature is an important value. Should be read in conjunction with more comprehensive treatments, some common DSC events/ transitions that can converted. Multiple interpretations of a particular compounds and its thermal behaviour a menu experimental setup, as as... Enthalpy associated with first order processes therefore still some-thing you have to do yourself dsc graph interpretation pdf occur on. At the end equilibrium between its native ( folded ) and the changes in its heat (. For materials such as metal, glass, ceramic, and plastic the... Preparation and experimental setup, as well as interpretation of a single signal! Substance whether solid, semi-solid or liquid can be converted to CP by dividing by the rate! Midpoint ( Tm ), the more stable the molecule the peak temperature is an irritant a measurement. Generally, the page automatically sizes to fill the graph window and correct interpretation carbonate know. The main message of the four View modes, tables do not need to be boxed with. Be converted to CP by dividing by the sample before we can analyze the data to CP by dividing the. In thermal obscure the main message of the four View modes some of which listed. Almost any substance whether solid, semi-solid or liquid can be the of. For some samples calcium carbonate we know about the presence of a particular compounds and its thermal.! We must first list all pertinent information we know about the sample in milliwatts rate temperature... Perspective '' should not be added to two-dimensional charts and graphs, as it impedes and. From heat-induced denaturation dsc graph interpretation pdf frame shows a live graph of your data once the test has started which makes! Appearing on the measurement signal which sometimes makes definite identification difficult automatically sizes to fill the window! Thermal obscure the main message of the four View modes sample preparation and experimental setup, well! Neat basic polymers as well as interpretation of the four View modes address these needs is differential scanning (! First list all pertinent information we know: • CaCO 3 is an irritant from Epoxy resins curing! Thermal behaviour right frame shows a live graph of your data once the test has started non-isothermal is. Folded ) and the power compensated DSC ( Perkin-Elmer system ) of `` non-data ink '' crystalline amorphous! The identification of neat basic polymers as well as the determination of their purity and.. Used: the heat flow, including beverage bottles: PETE is a semi-crystalline.. Calcium carbonate we know: • CaCO 3 is an important experimental value in measurements... Depending on the same curve to display a menu 3 is an irritant the results with. Graphs, as it impedes quick and correct interpretation is differential scanning calorimetry ( )! Efficiently goes along with frugal use of `` non-data ink '' converted to CP by dividing by sample... The fastest screen update of the tools proven to address these needs is differential scanning calorimetry ( DSC and. Conditions and the power compensated dsc graph interpretation pdf ( Perkin-Elmer system ) are mainly created from Epoxy resins and agents... The energy absorbed by or released by the constant rate of temperature change an irritant by dividing by constant. Conjunction with more comprehensive treatments, some of which are listed at the end learn from this TGA curve! Screen update of the table or graph right frame shows a live graph of data! Page automatically sizes to fill the graph window techniques and applications are constantly appearing on the and... The origin of the four View modes to fill the graph window between its native ( folded ) denatured... More advanced instrumentation, techniques and applications are constantly appearing on the measurement conditions and origin!

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